Relationship between electronegativity and melting point

Electronegativity - Wikipedia

relationship between electronegativity and melting point

Electronegativity - is the tendency of an atom to attract a bonding pair of electrons . That bond in a substance affects melting point, boling point. Chemistry. Is there any relationship between the polarity and the boiling point order of chemical (For High school understanding) melting and boiling points depend on: the different types of elements have different electronegativity values. Compounds that have hydrogen atoms bound to strongly electronegative atoms tend to have disproportionately high boiling points.

With a larger distance between the negatively-charged electron and the positively-charged nucleus, the force of attraction is relatively weaker.

Therefore, electron affinity decreases. Moving from left to right across a period, atoms become smaller as the forces of attraction become stronger. This causes the electron to move closer to the nucleus, thus increasing the electron affinity from left to right across a period. Note Electron affinity increases from left to right within a period. This is caused by the decrease in atomic radius. Electron affinity decreases from top to bottom within a group.

This is caused by the increase in atomic radius. Atomic Radius Trends The atomic radius is one-half the distance between the nuclei of two atoms just like a radius is half the diameter of a circle. However, this idea is complicated by the fact that not all atoms are normally bound together in the same way. Some are bound by covalent bonds in molecules, some are attracted to each other in ionic crystals, and others are held in metallic crystals.

Nevertheless, it is possible for a vast majority of elements to form covalent molecules in which two like atoms are held together by a single covalent bond. This distance is measured in picometers. Atomic radius patterns are observed throughout the periodic table. Atomic size gradually decreases from left to right across a period of elements. This is because, within a period or family of elements, all electrons are added to the same shell.

relationship between electronegativity and melting point

However, at the same time, protons are being added to the nucleus, making it more positively charged. The effect of increasing proton number is greater than that of the increasing electron number; therefore, there is a greater nuclear attraction.

This means that the nucleus attracts the electrons more strongly, pulling the atom's shell closer to the nucleus.

Electronegativity and Boiling Points

The valence electrons are held closer towards the nucleus of the atom. As a result, the atomic radius decreases. The valence electrons occupy higher levels due to the increasing quantum number n. Note Atomic radius decreases from left to right within a period.

This is caused by the increase in the number of protons and electrons across a period. Atomic radius increases from top to bottom within a group. This is caused by electron shielding. Melting Point Trends The melting points is the amount of energy required to break a bond s to change the solid phase of a substance to a liquid.


Because temperature is directly proportional to energy, a high bond dissociation energy correlates to a high temperature. Melting points are varied and do not generally form a distinguishable trend across the periodic table. However, certain conclusions can be drawn from the graph below. Metals generally possess a high melting point. Most non-metals possess low melting points. The non-metal carbon possesses the highest boiling point of all the elements.

The semi-metal boron also possesses a high melting point. Chart of Melting Points of Various Elements Metallic Character Trends The metallic character of an element can be defined as how readily an atom can lose an electron.

relationship between electronegativity and melting point

From right to left across a period, metallic character increases because the attraction between valence electron and the nucleus is weaker, enabling an easier loss of electrons. Metallic character increases as you move down a group because the atomic size is increasing.

When the atomic size increases, the outer shells are farther away. The principal quantum number increases and average electron density moves farther from nucleus. Note Metallic characteristics decrease from left to right across a period. Metallic characteristics increase down a group.

Molecular size also affects the melting point. When other factors are equal, smaller molecules melt at lower temperatures than larger molecules.

For example, the melting point of ethanol is Macromolecules have giant structures made up of many nonmetal atoms joined to adjacent atoms by covalent bonds. Substances with giant covalent structures, such as diamond, graphite and silica, have extremely high melting points because several strong covalent bonds must be broken before they can melt. Sciencing Video Vault Force of Attraction A strong attraction between molecules results in a higher melting point.

In general, ionic compounds have high melting points because the electrostatic forces connecting the ions — the ion-ion interaction — are strong. In organic compounds, the presence of polarity, especially hydrogen bonding, usually leads to a higher melting point.

Electronegativity and boiling point - The Student Room

The melting points of polar substances are higher than the melting points of nonpolar substances with similar sizes. Presence of Impurities Impure solids melt at lower temperatures and may also melt over a wider temperature range, known as melting point depression.

The melting point range for pure solids is narrow, usually only 1 to 2 degrees Celsius, known as a sharp melting point.